2011-06-30

Co.Exist

The Hydrogen Economy's Dirty Secret

Is hydrogen actually clean, or just clean compared to fossil fuels? Even though it mostly produces water, there are some nasty side effects no one is talking about.

Just when you think you can praise hydrogen as a squeaky-clean replacement for fossil fuels, someone has to spoil the scene by asking pesky questions about pollution.

Today, we think of coal, oil, and gas as "dirty" energy sources because they release heat-trapping carbon dioxide when you burn them, thereby contributing to global warming. Sometimes coal also contains sulfur, which makes nasty, lake-sterilizing sulfuric acid rain. One potential solution: Hydrogen, which makes nothing but benign water vapor when burned.

I've long been a fan of hydrogen, and have blogged in favor of it here. But nothing is perfect (except, perhaps, that classic guitar solo in "Blue Sky" from the Allman Brothers' Eat A Peach), and I'm now wondering about one possible blemish on hydrogen's otherwise shiny facade.

The problem isn't exactly with hydrogen itself, but with the machines we might burn it in. In order to ignite the hydrogen in a typical eco-vehicle's internal combustion engine, you need a spark—as in spark plugs. Such sparks provide the energy needed to oxidize the H2 into H2O, but there's a lot more than hydrogen and oxygen in the atmosphere. We normally think "oxygen" when we draw a breath of air, but nitrogen makes up 78% of it.

We don't use N2 gas for anything directly; it simply visits and exits our lungs as inert filler. But combine it with oxygen in the fiery cylinder of an internal combustion engine and you get "NOx" compounds such as nitrate, which forms nitric acid in raindrops. Such nitrogen fixation happens naturally, whenever lightning sizzles a strip of air. But we're doing it on a huge scale now, in vehicles whose spark-plug explosions amount to miniature lightning strikes.

This isn't all bad. Nitrogen fixation is how nitrogen gas becomes biologically useful, and at least a third of the protein in our bodies is built around artificially fixed nitrogen atoms. To make fertilizer, for example, factories blast hydrogen and nitrogen with electricity to form ammonia, an important plant food that eventually enters our own bodies through the global food web. Without this human-driven fixation, there simply wouldn't be enough active nitrogen available to keep so many billions of people alive.

But you can also have too much of a good thing. Here in the Adirondack Mountains of upstate New York, many of our 3,000 lakes and ponds are still chronically acidified by nitrogen-rich emissions from coal-fired power plants and from the millions of cars and trucks upwind of us in the mid-continent. Ecologists also worry that our forests and lakes face nutritional imbalances from airborne nitrogen overloads.

Hydrogen certainly has its detractors. Some call it a deceptive savior because
you have to burn fossil fuels in order to produce it, meaning that the
electricity needed for splitting water into its hydrogen and oxygen
components is likely to come from coal-fired power plants (though it can be derived from clean sources of
electricity, including hydro dams, solar hydrolysis, and the geothermal
power plants that Iceland is now counting on to support a hydrogen-based
transportation system).

Some detractors also say that the water vapor from hydrogen
combustion is itself a greenhouse gas, but they overlook the vast
amounts of water that evaporate from the oceans day and night without
parboiling us. Water vapor eventually condenses and falls out of the
atmosphere as rain or snow rather than remaining aloft for thousands of
years as CO2 does, so the climatic effects of hydrogen-car emissions
should be minimal.

So here's my pesky question. I assume that hydrogen vehicles would be nowhere near as harmful as today's gasoline-guzzlers when it comes to air pollution, if only because they don't release CO2. But if we just re-tool our engines to accept hydrogen rather than fossil fuels, won't we still be polluting the air, waters, and woods with nitrogen oxides?

There are ways to reduce NOx production from hydrogen-driven vehicles, or so I'm told by experts who know a lot more about this sort of thing than I do. Catalytic converters help, for example, as do certain engine designs. But I've not yet heard much discussion of this problem in the sustainable energy community, which tends to treat hydrogen like a flawless panacea.

Back when sulfuric and nitric acids in rain (aka acid rain) was still the primary environmental issue of note, media attention helped to pass clean-air legislation that reduced acidic sulfur emissions from coal-fired power plants. Now that global warming occupies center stage, it's easy to forget that the nitric half of the old acid rain problem was left largely unsolved.

So let's remember that there's more to air pollution than CO2 alone, and take advantage of the coming energy-transition to stop acid rain as well. Then when we claim to have found some clean alternatives to carbon-based fuels, perhaps we'll be telling the truth.

Update from the author:

For those of you who are following this string of comments, please note:

1. The focus of this mostly pro-hydrogen piece is a question about NOx emissions from internal combustions engines

2. Although many hydrogen
proponents support the use of technology other than internal combustion
engines in a future hydrogen economy, the proposed use of such engines
for hydrogen-burning is widely discussed on the web and in the technical
literature, including "International Journal of Hydrogen Energy" and
"Renewable Energy" (a Google search of "hydrogen internal combustion
engine emissions" or similar wording yields an abundance of hits)

3. As noted in the article,
the NOx emissions may indeed be reduced by converters and engine designs
(hence much of the engineering research mentioned above).  But they are
not totally prevented and can therefore represent a pollution problem.

4. Nitric acid pollution from internal combustion engines is an ongoing problem here in the northeast, hence my concern.

Thanks for your interest!

[Image by Flickr user Siemens PLM Software]

Curt Stager is an ecologist, paleoclimatologist, and science journalist with a Ph.D. in biology and geology from Duke University. His new book is DEEP FUTURE: The Next 100,000 Years of Life on Earth (St. Martin's Press, March 2011).

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1 Comments

  • kimgyr

    PS. I have also written about the evolution of the Earth's crust on a cooling and contracting planet, and the implications and evolution of continents and the lifeforms that inhabit it - your research and mine may interact in some very interesting ways.

    As the Earth has cooled, it has also contracted (Lord Kelvin's "Secular Cooling") changing its shape from that of a grape to that of a raisin in the process. It would once have been entirely covered by shallow oceans; now in its raisin form, it has ridges and folds, which may have occurred suddenly with the impact of the meteor that created the Chixulub Crater off the coast of Yucatan to allow it to contract suddenly when the integrity of its spherical shell was broken.

    The evidence for this is both the Grand Canyon, cut miles deep through sedimentary rock, and the buttes out west with no rubble at their bases, indicating the very sudden emergence of the sea floor from the sea. That sea drained off the continent to create both the Grand Canyon and the Baja Peninsula with the tremendous volume of water involved. Its rapidity washed all the rubble away from the base of the buttes, and swept semi-aquatic dinosaurs away to pile their bones up at Dinsaur National Monument and on the North Slope of Alaska.

    That dinosaurs could exist at all both in Alaska and now under the ice in Antarctica is evidence that there were no continents, the seas extended to the poles, and carried heat to them in currents just as the Gulf Stream and the Humboldt Current do today. The large sauropods, with their long necks and browsing duckbills, and the therapods with their top-of-the-skull eye sockets and nostrils, long vertical-section tails, and small forelimbs could have snuck up on them before making a final lunge and disemboweling them with their sickle claws, as had Velociraptor.

    I can send you a PDF with a lot more detail if you can supply me with an email address. Please reply to humansolutions@ greenmillennium.eu